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This book is designed to suit the needs of the senior and graduate metallurgist in acquainting him with the fundamentals of the physical chemistry and the thermodynamics of metals and metallurgical processes. In this book the attempt is made to include this physical chemistry in simple terms and to present the fundamentals of chemical thermodynamics so that the student may be able to understand the thermodynamic method and apply it to metallurgical problems. The first portion summarizes modern views on the chemistry of the metallic state and briefly sketches the chemistry of other states with which the metallurgist must perforce deal. The later portions deal with thermodynamics, the treatment being mostly in the classical manner but with metallurgical applications and limitations always in mind. The sections on heterogeneous equilibrium discuss in some detail phases of variable composition, since these are common place at elevated temperature, particularly in metallurgical systems. The

The thermodynamic aspects of corrosion and, more generally, electrochemistry are quite complex, yet are most important to understanding the driving forces behind them. This chapter sets the stage for the remaining chapters on surface films; it is not a detailed dissertation on the thermodynamics of corrosion.

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